本書采用英漢兩種語言，英文為先，中英文并重。參照國內(nèi)成熟的分析化學(xué)實(shí)驗教材內(nèi)容，結(jié)合本校多年來的教學(xué)實(shí)踐，同時參照國外原版分析化學(xué)實(shí)驗指導(dǎo)書的英文內(nèi)容編寫而成。全書分四章，第一章是分析化學(xué)實(shí)驗的基礎(chǔ)知識；第二章是定量分析基本操作；第三章是定量分析實(shí)驗；第四章常用的分離方法實(shí)驗。另外，書中增加了部分綜合設(shè)計實(shí)驗，有助于學(xué)生在掌握基本操作的同時，培養(yǎng)解決實(shí)際問題的能力，養(yǎng)成嚴(yán)謹(jǐn)、求實(shí)、創(chuàng)新的科學(xué)態(tài)度。
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目錄
前言
Chapter 1 Basic Knowledge of Analytical Chemistry Experiments 1
1.1 Basic Requirements for Analytical Chemistry Experiments 1
1.2 Basic Knowledge of the Laboratory 1
Chapter 2 Basic Operation for Quantitative Analysis 8
2.1 Analytical Balance 8
2.2 Pipetting and Constant Volume Operation 10
2.3 Burette and Basic Operations for Titration Analysis 13
2.4 Basic Operations of Gravimetric Analysis 16
Chapter 3 Quantitative Analysis Experiments 23
3.1 Basic Operation Practices 23
Exp.1 Practices of Analytical Balance 23
Exp.2 Practices of Basic Operation for Titration Analysis 24
3.2 Acid-base Titration Experiments 27
Exp.3 Preparation and Standardization of NaOH Standard Solution 27
Exp.4 Preparation and Standardization of HCl Solution 29
Exp.5 Determination of Boric Acid in Food Additives 31
Exp.6 Analysis of Mixed Alkali 33
Exp.7 Determination of Nitrogen in Ammonium Salts 35
Exp.8 Determination of Total Phosphorus in Phosphate Fertilizer 37
Exp.9 Determination of Total Acidity in Edible Vinegar 39
Exp.10 Determination of the Molar Mass of Organic Acids 41
3.3 Complexometric Titration Experiments 43
Exp.11 Preparation and Standardization of EDTA Standard Solution and Determination of Water Hardness 43
Exp.12 Determination of Calcium and Magnesium in Industrial Raw Materials 46
Exp.13 Determination of Pb2+ and Bi3+ in Mixture of Pb2+ and Bi3+ 49
Exp.14 Determination of Aluminum and Magnesium in Gastropine Tablet 51
Exp.15 Determination of EDTA in Detergents 54
Exp.16 Determination of Iron, Aluminum, Calcium and Magnesium in Cement Clinker 56
Exp.17 Determination of Aluminum in Industrial Aluminum Sulfate 60
3.4 Redox Titration Experiments 63
Exp.18 Preparation and Standardization of Potassium Permanganate Standard Solution and Determination of H2O2 63
Exp.19 Determination of Iron in Iron Ore by Potassium Dichromate Method(Mercury-Free Method) 65
Exp.20 Determination of Chemical Oxygen Demand in Environmental WaterSamples (KMnO4 Method) 67
Exp.21 Determination of Chemical Oxygen Demand in Sewage (K2Cr2O7 Method) 70
Exp.22 Determination of Copper in Copper Salt by Indirect Iodimetry 74
Exp.23 Determination of Calcium in Calcium Preparations 76
Exp.24 Determination of Dissolved Oxygen in Water 78
Exp.25 Determination of Vitamin C in Juice 81
Exp.26 Determination of Glucose in Glucose Injection 83
3.5 Precipitation Titration and Gravimetric Analysis Experiments 85
Exp.27 Determination of Chlorine in Soluble Chloride by Mohr Method 85
Exp.28 Determination of Chlorine in Soluble Chloride by Vollhard Method 87
Exp.29 Determination of Barium in Barium Salt by Gravimetric Method 89
Exp.30 Determination of Barium in Barium Salts (Microwave Drying Gravimetric Method) 91
Exp.31 Determination of Potassium in Fertilizer 93
Exp.32 Determination of Nickel in Steel 95
Chapter 4 Spectrophotometry and Common Separation Methods Experiments 98
Exp.33 Spectrophotometric Determination of Iron with Phenanthroline 98
Exp.34 Determination of NO2– in Food 101
Exp.35 Determination of Available Phosphorus in Soil 103
Exp.36 Determination of Total Flavonoids in Bamboo Leaves by Spectrophotometry Coupled with Microwave-assisted Extraction Technique 105
Exp.37 Determination of Trace Lead in Environmental Water Samples by Extraction Separation-spectrophotometry 107
Exp.38 Separation and Identification of Amino Acids by Paper Chromatography 110
Exp.39 Separation of Food Pigments by Paper Chromatography 112
Chapter 5 Comprehensive Design Experiments 115
5.1 Acid-base Titration Design Experiments 115
Exp.40 Determination of SiO2 by Potassium Fluosilicate Method 115
Exp.41 Determination of NaHCO3 and Na2CO3 in Biscuits 116
Exp.42 Determination of Boron Trioxide of Slag 116
5.2 Complexometric Titration Design Experiments 117
Exp.43 Determination of ZnO in Calamine Lotion 117
Exp.44 Determination of Nickel and Magnesium in Nickel-magnesium Alloys 117
Exp.45 Determination of Each Component in Mixture of Mg2+ and EDTA 118
5.3 Redox Titration Design Experiments 118
Exp.46 Determination of Chromium in Alloys 118
Exp.47 Determination of Iodine in Iodized Salt 119
Exp.48 Determination of Ferrous Oxide in Iron-containing Steel Slag 119
5.4 Precipitation Titration Design Experiments 120
Exp.49 Determination of Sodium Chlorine in Food 120
Exp.50 Determination of Chloride Ion in Complex Fertilizer 120
Exp.51 Determination of Silver in Nylon Silver-plated Fiber 121
5.5 Spectrophotometry Design Experiments 121
Exp.52 Determination of Chromium and Manganese in Steel by Spectrophotometry 121
Exp.53 Determination of Trace Chlorine in Air 122
Exp.54 Determination of Lead in Plant Leaves by Spectrophotometry 122
5.6 Comprehensive Experiments 123
Exp.55 Preparation and Composition Determination of Potassium Copper (Ⅱ) Dioxalate 123
Exp.56 Preparation of Sodium Thiosulfate and Determination of Product Content 124
Exp.57 Determination of Zinc Oxide and Boron Trioxide in Flame Retardants 126Appendix 127
Appendix 1 Preparation of Commonly Used Buffer 127
Appendix 2 Commonly Used Indicator 127
Appendix 3 Concentrations and Densities of Common Acid-base Solutions 130
Appendix 4 Common Primary Standard and Their Drying Conditions and Applications 130
Appendix 5 Molecular Weight of Common Compounds 131
第1章 分析化學(xué)實(shí)驗基本知識 133
1.1 分析化學(xué)實(shí)驗的基本要求 133
1.2 實(shí)驗室基本知識 133
第2章 定量分析基本操作 139
2.1 分析天平 139
2.2 移液和定容操作 140
2.3 滴定管及滴定分析基本操作 143
2.4 重量分析法的基本操作 146
第3章 定量分析實(shí)驗 151
3.1 基礎(chǔ)操作練習(xí) 151
實(shí)驗1 分析天平稱量練習(xí) 151
實(shí)驗2 滴定分析基本操作練習(xí) 152
3.2 酸堿滴定實(shí)驗 154
實(shí)驗3 NaOH標(biāo)準(zhǔn)溶液的配制和標(biāo)定 154
實(shí)驗4 HCl溶液的配制和標(biāo)定 156
實(shí)驗5 食品添加劑中硼酸含量的測定 157
實(shí)驗6 混合堿的分析 159
實(shí)驗7 銨鹽中氮含量的測定 161
實(shí)驗8 磷肥中全磷的測定 163
實(shí)驗9 食用醋總酸度的測定 164
實(shí)驗10 有機(jī)酸摩爾質(zhì)量的測定 165
3.3 絡(luò)合滴定實(shí)驗 167
實(shí)驗11 EDTA標(biāo)準(zhǔn)溶液的配制、標(biāo)定和水硬度的測定 167
實(shí)驗12 工業(yè)原料中鈣、鎂含量的測定 170
實(shí)驗13 鉛、鉍混合溶液中鉛、鉍含量的測定 172
實(shí)驗14 胃舒平片中鋁和鎂含量的測定 174
實(shí)驗15 洗滌劑中EDTA含量的測定 176
實(shí)驗16 水泥熟料中鐵、鋁、鈣、鎂含量的測定 178
實(shí)驗17 工業(yè)硫酸鋁中鋁含量的測定 181
3.4 氧化還原滴定實(shí)驗 183
實(shí)驗18 高錳酸鉀標(biāo)準(zhǔn)溶液的配制、標(biāo)定和H2O2含量的測定 183
實(shí)驗19 重鉻酸鉀法測定鐵礦石中的鐵含量(無汞法) 186
實(shí)驗20 環(huán)境水樣中化學(xué)需氧量的測定(KMnO4法) 187
實(shí)驗21 污水中化學(xué)需氧量的測定(K2Cr2O7法) 190
實(shí)驗22 間接碘量法測定銅鹽中的銅含量 193
實(shí)驗23 鈣制劑中鈣含量的測定 195
實(shí)驗24 水中溶解氧的測定 196
實(shí)驗25 果汁中維生素C含量的測定 199
實(shí)驗26 葡萄糖注射液中葡萄糖含量的測定 201
3.5 沉淀滴定及重量分析法實(shí)驗 202
實(shí)驗27 莫爾法測定可溶性氯化物中的氯含量 202
實(shí)驗28 福爾哈德法測定可溶性氯化物中的氯含量 204
實(shí)驗29 重量分析法測定鋇鹽中的鋇含量 206
實(shí)驗30 鋇鹽中鋇含量的測定(微波干燥重量法) 208
實(shí)驗31 肥料中鉀含量的測定 210
實(shí)驗32 鋼鐵中鎳含量的測定 211
第4章 分光光度法及常用分離方法實(shí)驗 214
實(shí)驗33 鄰二氮菲分光光度法測定鐵 214
實(shí)驗34 食品中NO2-含量的測定 216
實(shí)驗35 土壤中有效磷的測定 218
實(shí)驗36 微波輔助萃取-分光光度法測定竹葉中總黃酮 219
實(shí)驗37 萃取分離-分光光度法測定環(huán)境水樣中微量鉛 221
實(shí)驗38 紙色譜法分離和鑒定氨基酸 223
實(shí)驗39 紙色譜法分離食用色素 225
第5章 綜合設(shè)計實(shí)驗 227
5.1 酸堿滴定設(shè)計實(shí)驗 227
實(shí)驗40 氟硅酸鉀法測定SiO2 227
實(shí)驗41 餅干中NaHCO3和Na2CO3含量的測定 227
實(shí)驗42 礦渣中三氧化二硼的測定 228
5.2 絡(luò)合滴定設(shè)計實(shí)驗 228
實(shí)驗43 爐甘石洗劑中ZnO含量的測定 229
實(shí)驗44 鎳鎂合金中鎳、鎂的測定 229
實(shí)驗45 Mg2+-EDTA混合液中各組分的測定 229
5.3 氧化還原滴定設(shè)計實(shí)驗 230
實(shí)驗46 合金中鉻含量的測定 230
實(shí)驗47 加碘食鹽中碘含量的測定 230
實(shí)驗48 含鐵鋼渣中氧化亞鐵含量的測定 230
5.4 沉淀滴定設(shè)計實(shí)驗 231
實(shí)驗49 食品中氯化鈉的測定 231
實(shí)驗50 復(fù)合肥料中氯離子含量的測定 231
實(shí)驗51 尼龍鍍銀纖維中銀含量的測定 231
5.5 分光光度法設(shè)計實(shí)驗 232
實(shí)驗52 分光光度法測定鋼樣中的鉻和錳 232
實(shí)驗53 空氣中微量氯氣的測定 232
實(shí)驗54 分光光度法測定植物葉中的鉛含量 233
5.6 其他綜合實(shí)驗 233
實(shí)驗55 二草酸根合銅(Ⅱ)酸鉀的制備及組成測定 233
實(shí)驗56 硫代硫酸鈉的制備及產(chǎn)物含量的測定 234
實(shí)驗57 阻燃劑中氧化鋅和三氧化二硼的測定 235
附錄 236
附錄1 常用緩沖溶液的配制 236
附錄2 常用指示劑 236
附錄3 常用酸堿溶液的濃度和密度 239
附錄4 常用基準(zhǔn)物質(zhì)及其干燥條件與應(yīng)用 239
附錄5 常用化合物的分子量 240
主要參考文獻(xiàn) 242
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