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有機(jī)化學(xué)(魏榮寶) 讀者對(duì)象:《有機(jī)化學(xué)》可作為高等學(xué)校化學(xué)、化工、藥學(xué)、材料、環(huán)境、輕工、食品等專業(yè)的有機(jī)化學(xué)課程的教材,也可供有機(jī)化學(xué)領(lǐng)域的科研工作者參考。
《有機(jī)化學(xué)》共分十二章,首先介紹基本知識(shí),讓學(xué)生對(duì)有機(jī)化學(xué)全貌有個(gè)基本了解,為后續(xù)學(xué)習(xí)打下基礎(chǔ)。而后按碳-碳單鍵、碳-碳重鍵、碳-雜單鍵、碳-雜雙鍵等化學(xué)鍵的類型為主線進(jìn)行編寫,以利于學(xué)生對(duì)比學(xué)習(xí)和總結(jié)。加強(qiáng)了有機(jī)化學(xué)中規(guī)律的總結(jié),如:D-A 反應(yīng)的1,2,3,4,5,6規(guī)律;Claisen和Cope重排中的3,3斷裂、1,1相連、雙鍵移位;氧化數(shù)法判斷有機(jī)基團(tuán)的順序;輪烯芳香性的簡單判斷法;熱消除反應(yīng)中的 ABCDE規(guī)律;取代苯環(huán)上氫1H NMR裂分規(guī)律等。介紹了旋光方向與構(gòu)型對(duì)應(yīng)的Lowe經(jīng)驗(yàn)規(guī)律;異頭效應(yīng)與螺共軛效應(yīng)等知識(shí)。本書采用中國化學(xué)會(huì)2017版最新的命名原則。
《有機(jī)化學(xué)》可作為高等學(xué);瘜W(xué)、化工、藥學(xué)、材料、環(huán)境、輕工、食品等專業(yè)的有機(jī)化學(xué)課程的教材,也可供有機(jī)化學(xué)領(lǐng)域的科研工作者參考。
魏榮寶,天津理工大學(xué)化學(xué)化工學(xué)院,教授,天津理工大學(xué)化學(xué)化工學(xué)院的有機(jī)化學(xué)是天津市精品課程,作者是天津市教學(xué)名師,天津市教學(xué)楷模;主編和編寫組成員已完成國家自然科學(xué)基金10余項(xiàng),發(fā)表研究論文400余篇。其中多篇發(fā)表在國外一區(qū)或二區(qū)期刊上,在國內(nèi)外有一定的影響力。
第1章 有機(jī)化學(xué)的基礎(chǔ)知識(shí) 1
1.1 有機(jī)化合物的一般特點(diǎn)(characteristic of organic compound) 1 1.2 共價(jià)鍵的屬性(feature of covalent bond) 1 1.3 分子式、構(gòu)造式、構(gòu)型式和構(gòu)象式(molecular formula, constitution,configuration and conformation) 3 1.4 氫鍵(hydrogen bond) 4 1.5 有機(jī)化合物的分類(classification of organic compound) 5 1.6 簡單有機(jī)化合物的命名(nomenclature of simple organic compound) 7 1.6.1 烷烴的命名(nomenclature of alkane) 7 1.6.2 單環(huán)烷烴的命名(nomenclature of mono cycloalkane) 9 1.6.3 橋環(huán)烴的命名(nomenclature of bridged alkane) 10 1.6.4 螺環(huán)烴的命名(nomenclature of spirocyclic alkane) 12 1.6.5 烯烴的命名(nomenclature of alkene) 13 1.6.6 炔烴的命名(nomenclature of alkyne) 14 1.6.7 二烯烴的命名(nomenclature of diene) 15 1.6.8 芳烴的命名(nomenclature of arene) 15 1.6.9 鹵代烴的命名(nomenclature of halohydrocarbon) 17 1.6.10 醇的命名(nomenclature of alcohol) 18 1.6.11 酚的命名(nomenclature of phenol) 18 1.6.12 醚的命名(nomenclature of ether) 19 1.6.13 簡單醛、酮的命名(nomenclature of simple aldehyde and ketone) 19 1.6.14 簡單羧酸及其衍生物的命名(nomenclature of simple carboxylic acid and derivatives) 20 1.6.15 硝基化合物的命名(nomenclature of nitro compound) 21 1.6.16 胺類化合物的命名(nomenclature of amines) 21 習(xí)題(Problems) 21 1.7 氧化數(shù)(oxidation number) 21 1.7.1 電負(fù)性(electronegativity) 21 1.7.2 氧化數(shù)值(oxidation value) 22 1.7.3 用氧化數(shù)法確定有機(jī)基團(tuán)的大小(determination of sequence of organic group by oxidation number) 22 1.7.4 用氧化數(shù)法處理氧化還原滴定結(jié)果(handling redox titration data by oxidation number) 23 1.8 廣義酸堿理論(theory of generalized acids and bases) 24 1.9 有機(jī)化合物中碳的構(gòu)型(configuration of carbon in organic compound) 27 1.10 共振論與分子軌道理論(resonance theory and molecular orbital theory) 31 1.11 有機(jī)化合物的波譜簡介(introduction to spectroscopy of organic compound) 34 1.11.1 紫外光譜(ultraviolet spectrum) 34 1.11.2 紅外光譜(infrared spectrum) 37 1.11.3 核磁共振波譜(nuclear magnetic resonance spectroscopy) 43 1.11.4 質(zhì)譜(mass spectrum) 51 習(xí)題(Problems) 54 第2章 碳-碳單鍵化合物 55 2.1 烷烴(alkane) 55 2.1.1 烷烴的物理性質(zhì)及波譜(physical properties and spectrum of alkane) 55 2.1.2 烷烴的同分異構(gòu)(isomerism of alkane) 57 2.1.3 烷烴的構(gòu)象(conformation of alkane) 59 2.1.4 烷烴的化學(xué)性質(zhì)(chemical properties of alkane) 61 2.1.5 烷烴的來源(source of alkane) 64 2.2 環(huán)烷烴(cycloalkane) 65 2.2.1 環(huán)烷烴的分類和命名(classification and nomenclature of cycloalkane) 65 2.2.2 環(huán)烷烴的構(gòu)象(conformation of cycloalkane) 66 2.2.3 環(huán)烷烴的反應(yīng)(reaction of cycloalkane) 71 2.2.4 小環(huán)烷烴的制備(preparation of small-cycloalkane) 72 2.2.5 奇妙的立方烷(wonderful cubane)* 72 習(xí)題(Problems) 73 第3章 碳-碳重鍵化合物 74 3.1 分類及結(jié)構(gòu)(classification and structure) 74 3.2 同分異構(gòu)現(xiàn)象(isomerism) 75 3.3 物理性質(zhì)及波譜(physical properties and spectrum) 77 3.4 化學(xué)性質(zhì)(chemical properties) 78 3.4.1 親電加成反應(yīng)(electrophilic addition) 78 3.4.2 親電加成反應(yīng)的機(jī)理(mechanism of electrophilic addition) 84 3.4.3 馬氏加成與反馬氏加成(Markovnikov and anti-Markovnikov addition) 88 3.4.4 加氫反應(yīng)(hydrogenation reaction) 89 3.4.5 α-氫的反應(yīng)(reaction of α-hydrogen) 90 3.4.6 氧化反應(yīng)(oxidation reaction) 90 3.4.7 自由基加成及機(jī)理(mechanism of radical addition) 92 3.4.8 卡賓的加成反應(yīng)(addition reaction of carbene) 92 3.4.9 親核加成反應(yīng)(nucleophilic addition reaction) 92 3.4.10 炔氫的反應(yīng)(reaction of acetylenic hydrogen) 93 3.4.11 二烯烴的1,2-加成和1,4-加成反應(yīng)(1,2-and 1,4-addition of diene) 94 3.4.12 聚合反應(yīng)(polymerization) 95 3.4.13 烯烴的復(fù)分解反應(yīng)(metathesis of alkene) 97 3.5 誘導(dǎo)效應(yīng)和共軛效應(yīng)(inductive effect and conjugated effect) 97 3.5.1 誘導(dǎo)效應(yīng)(inductive effect) 97 3.5.2 共軛效應(yīng)與超共軛效應(yīng)(conjugated effect and hyperconjugative effect) 98 3.6 電環(huán)化與環(huán)加成反應(yīng)(electrocyclic reaction and cycloaddition reaction) 100 3.6.1 電環(huán)化反應(yīng)(electrocyclic reaction) 100 3.6.2 環(huán)加成反應(yīng)(cycloaddition reaction) 103 3.7 烯烴和炔烴的制備(preparation of alkene and alkyne) 108 3.7.1 烯烴的制備(preparation of alkene) 108 3.7.2 炔烴的制備(preparation of alkyne) 109 3.8 螺環(huán)烯烴與螺共軛效應(yīng)(spirocycloalkenes and spiroconjugation effect)* 110 習(xí)題(Problems) 111 第4章 芳烴及芳香性 114 4.1 芳烴(arene) 114 4.1.1 芳烴的分類(classification of arene) 114 4.1.2 芳烴的物理性質(zhì)及波譜(physical properties and spectrum of arene) 115 4.1.3 苯的結(jié)構(gòu)(structure of benzene) 115 4.1.4 苯環(huán)上的親電取代反應(yīng)(electrophilic substitution of benzene ring) 118 4.1.5 苯環(huán)上的定位效應(yīng)(directing effect on benzene ring) 124 4.1.6 苯環(huán)上的親核取代反應(yīng)(nucleophilic substitution on benzene ring) 130 4.1.7 苯環(huán)上的加成反應(yīng)(addition reaction on benzene ring) 132 4.1.8 苯環(huán)上側(cè)鏈的反應(yīng)(reaction of branched chain on benzene ring) 133 4.1.9 芳烴的來源及制備(source and preparation of arene) 134 4.2 多環(huán)芳烴(polycyclic arene) 135 4.2.1 分類(classification) 135 4.2.2 聯(lián)苯(biphenyl) 136 4.2.3 萘(naphthalene) 136 4.2.4 蒽(anthracene) 141 4.2.5 菲(phenanthrene) 143 4.2.6 其他稠環(huán)芳烴(other fused ring aromatic hydrocarbons) 143 4.2.7 Haworth合成(Haworth synthesis) 143 4.2.8 多苯代脂烴(polyphenyl hydrocarbons) 145 4.2.9 富勒烯(fullerene) 146 4.2.10 稠環(huán)化合物的命名(nomenclature of fused ring aromatic hydrocarbons) 147 4.3 芳香性, 非芳香性, 反芳香性, 同芳香性及反同芳香性(aromaticity,nonaromaticity, antiaromaticity, homoaromaticity and antihomoaromaticity) 147 4.4 致癌芳烴(carcinogenic arene) 153 習(xí)題(Problems) 154 第5章 手性化合物與手性合成 157 5.1 簡介(introduction) 157 5.2 平面偏振光(plane polarized light) 158 5.3 旋光性、旋光物質(zhì)與比旋光度(optical rotation, optically active substance and specific rotation) 158 5.4 分子的對(duì)稱性(molecular symmetry) 159 5.5 構(gòu)型表示與標(biāo)記(determination configuration) 162 5.5.1 Fischer投影式(Fischer projection formula) 162 5.5.2 D-L構(gòu)型標(biāo)記法(method of D-L-configuration labeling) 164 5.5.3 R-S 構(gòu)型標(biāo)記法(method of R-S-configuration labeling) 164 5.6 含一個(gè)手性碳原子的光學(xué)異構(gòu)體(optical isomer of one chiral carbon atom) 167 5.7 含兩個(gè)手性碳原子的光學(xué)異構(gòu)體(optical isomer of two chiral carbon atoms) 168 5.7.1 含兩個(gè)不同手性碳原子的光學(xué)異構(gòu)體(optical isomer of distinct two chiral carbon atoms) 168 5.7.2 含兩個(gè)相似手性碳原子的光學(xué)異構(gòu)體(optical isomer of similar two chiral carbon atoms) 168 5.8 含多個(gè)手性碳原子的光學(xué)異構(gòu)體(optical isomer of multiple chiral carbon atoms) 169 5.9 環(huán)狀手性化合物(chiral compound of cyclo-hydrocarbon) 169 5.10 不含手性碳原子的光學(xué)異構(gòu)體(optical isomer of non-containing chiral carbon atom) 170 5.10.1 含手性軸的化合物(compounds of containing chiral axis) 170 5.10.2 含手性面的化合物(compounds of containing chiral plane) 172 5.10.3 螺旋化合物(screw compound) 173 5.11 外消旋體的合成與拆分(synthesis and resdution of racemate) 173 5.12 旋光方向與構(gòu)型的關(guān)系(rotatory direction and configuration) 174 習(xí)題(Problems) 175 第6章 碳-鹵極性單鍵化合物 178 6.1 脂肪鹵代烴(aliphatic halohydrocarbons) 178 6.1.1 鹵代烴的分類(classification of halohydrocarbons) 178 6.1.2 鹵代烴的物理性質(zhì)及波譜(physical properties and spectrum of halohydrocarbons) 179 6.1.3 鹵代烴的親核取代反應(yīng)(nucleophilic substitution of halohydrocarbons) 179 6.1.4 親核取代反應(yīng)的機(jī)理(mechanism of nucleophilic substitution) 182 6.1.5 影響反應(yīng)歷程的因素(influencing factor of reaction mechanism) 186 6.1.6 消除反應(yīng)(elimination reaction) 193 6.1.7 與金屬的反應(yīng)(reaction with metals) 197 6.2 芳香鹵代烴(halogenated aromatic hydrocarbons) 198 6.2.1 芳香鹵代烴的結(jié)構(gòu)特征(structural feature of halogenated aromatic hydrocarbons) 198 6.2.2 鹵苯的反應(yīng)(reaction of halobenzene) 199 6.3 鹵代烴的制備(preparation of halohydrocarbons) 200 6.4 重要的鹵代烴(important halohydrocarbons) 202 習(xí)題(Problems) 203 第7章 碳-氧(硫) 極性單鍵化合物 206 7.1 醇類(alcohols) 206 7.1.1 醇的結(jié)構(gòu)、分類和異構(gòu)(structure, classification and isomerism of alcohols) 206 7.1.2 醇的物理性質(zhì)及波譜(physical properties and spectrum of alcohols) 208 7.1.3 醇的化學(xué)性質(zhì)(chemical properties of alcohols) 210 7.1.4 醇的制備(preparation of alcohols) 214 7.1.5 多元醇(polyalcohols) 215 7.2 醚類(ethers) 219 7.2.1 醚的結(jié)構(gòu)、分類、異構(gòu)和命名(structure, classification, isomerism and nomenclature of ethers) 219 7.2.2 醚的物理性質(zhì)及波譜(physical properties and spectrum of ethers) 220 7.2.3 醚的化學(xué)性質(zhì)(chemical properties of ethers) 221 7.2.4 環(huán)氧乙烷(epoxyethane) 223 7.2.5 冠醚(crown ether) 225 7.3 酚類(phenols) 226 7.3.1 酚的結(jié)構(gòu)(structure of phenols) 226 7.3.2 酚的物理性質(zhì)及波譜(physical properties and spectrum of phenols) 226 7.3.3 酚的化學(xué)性質(zhì)(chemical properties of phenols) 227 7.3.4 多元酚(polyphenols) 234 7.3.5 酚的制備(preparation of phenols) 235 習(xí)題(Problems) 236 7.4 硫醇和硫醚(thiol and thioether) 239 7.4.1 制備(preparation) 239 7.4.2 物理性質(zhì)(physical properties) 239 7.4.3 化學(xué)性質(zhì)(chemical properties) 239 7.5 芳磺酸(aromatic sulfonic acid) 240 7.5.1 芳磺酸的命名(nomenclature of aromatic sulfonic acid) 240 7.5.2 芳磺酸的制備(preparation of aromatic sulfonic acid) 241 7.5.3 芳磺酸的物理性質(zhì)(physical properties of aromatic sulfonic acid) 241 7.5.4 芳磺酸的化學(xué)性質(zhì)(chemical properties of aromatic sulfonic acid) 242 7.5.5 芳磺酰氯和芳磺酰胺(aromatic sulfonyl chloride and aromatic sulfamine) 243 7.5.6 烷基苯磺酸鈉和表面活性劑(alkyl benzene sulfonic acid sodium and surfactant) 245 7.5.7 離子交換樹脂(ion exchange resin) 245 第8章 碳-氧極性重鍵化合物——醛和酮 247 8.1 醛、酮的結(jié)構(gòu)、分類及命名(structure, classification and nomenclature of aldehyde and ketone) 247 8.2 醛、酮的物理性質(zhì)及波譜(physical properties and spectrum of aldehyde and ketone) 248 8.3 醛、酮的親核加成反應(yīng)(nucleophilic addition reaction of aldehyde and ketone) 250 8.3.1 與氫氰酸的加成(addition reaction with hydrocyanic acid) 251 8.3.2 與亞硫酸氫鈉的加成(addition reaction with sodium bisulfite) 252 8.3.3 與醇的加成(addition reaction with alcohol) 252 8.3.4 與水的加成(addition reaction with water) 254 8.3.5 與金屬有機(jī)化合物的加成(reaction with organometallic compound) 255 8.3.6 與氨及其衍生物的加成縮合反應(yīng)(reaction with ammonia and its derivatives) 257 8.3.7 Wittig反應(yīng)(Wittig reaction) 259 8.4 α-氫的反應(yīng)(reaction of α-hydrogen) 259 8.4.1 鹵化反應(yīng)(halogenating reaction) 260 8.4.2 羥醛縮合反應(yīng)(aldol condensation) 261 8.4.3 Perkin反應(yīng)(Perkin reaction) 265 8.4.4 Mannich反應(yīng)(Mannich reaction) 265 8.5 氧化還原反應(yīng)(redox reaction) 266 8.5.1 與Tollen試劑和Fehling試劑反應(yīng)(reaction with Tollen and Fehling reagent) 266 8.5.2 還原成醇(reduction to alcohol) 267 8.5.3 Meerwein-Ponndorf還原(Meerwein-Ponndorf reduction) 268 8.5.4 Clemmensen還原(Clemmensen reduction) 268 8.5.5 Wolff-Kishner-黃鳴龍還原(Wolff-Kishner-Huang Minlon reduction) 268 8.5.6 Cannizzaro反應(yīng)(Cannizzaro reaction) 269 8.5.7 安息香縮合(benzoin condensation) 269 8.5.8 二苯酮重排(benzophenone rearrangement) 270 8.5.9 Baeyer-Villiger重排(Baeyer-Villiger rearrangement) 271 8.5.10 Favorskii重排(Favorskii rearrangement) 271 8.6 α,β-不飽和醛、酮的性質(zhì)(properties of α,β-unsaturated aldehyde and ketone) 271 8.7 醛、酮的制備(preparation of aldehyde and ketone) 273 8.8 重要的醛、酮(important aldehyde, ketone) 276 習(xí)題(Problems) 280 第9章 碳-氧極性重鍵化合物——羧酸及其衍生物 282 9.1 羧酸(carboxylic acid) 282 9.1.1 羧酸的結(jié)構(gòu)(structure of carboxylic acid) 282 9.1.2 羧酸的分類和命名(classification and nomenclature of carboxylic acid) 283 9.1.3 羧酸的物理性質(zhì)及波譜(physical properties and spectrum of carboxylic acid) 284 9.1.4 羧酸的化學(xué)性質(zhì)(chemical properties of carboxylic acid) 286 9.1.5 二元羧酸的熱分解反應(yīng)(thermal decomposition reaction of dicarboxylic acid) 292 9.1.6 羥基酸 (hydroxyl acid) 293 9.1.7 羧酸的制備(preparation of carboxylic acid) 294 習(xí)題(Problems) 297 9.2 羧酸衍生物(carboxylic acid derivatives) 298 9.2.1 分類和命名(classification and nomenclature) 298 9.2.2 物理性質(zhì)及波譜(physical properties and spectrum) 299 9.2.3 水解、醇解、氨解反應(yīng) (hydrolysis, alcoholysis and aminolysis) 300 9.2.4 與金屬有機(jī)化合物的反應(yīng)(reaction with organometallic compound) 304 9.2.5 還原反應(yīng)(reduction reaction) 305 9.2.6 酯縮合反應(yīng)(ester condensation) 306 9.2.7 Hofmann重排(Hofmann rearrangement) 307 9.2.8 有關(guān)NBS的一些反應(yīng) (reactions about NBS) 307 9.2.9 有關(guān)丙二酸二乙酯和乙酰乙酸乙酯的反應(yīng) (reactions about diethyl malonate and ethyl acetoacetate) 308 9.2.10 Knoevenagel反應(yīng) (Knoevenagel reaction) 311 9.2.11 Michael加成 (Michael addition) 312 9.2.12 Weiss反應(yīng)(Weiss reaction) 313 習(xí)題(Problems) 314 第10章 碳-氮極性單鍵化合物 318 10.1 硝基化合物(nitro compound) 318 10.1.1 硝基化合物的分類及命名(classification and nomenclature of nitro compound) 318 10.1.2 硝基化合物的物理性質(zhì)及波譜 (physical properties and spectrum of nitro compound) 319 10.1.3 硝基化合物的化學(xué)性質(zhì)(chemical properties of nitro compound) 320 10.2 胺類(amines) 326 10.2.1 胺類的結(jié)構(gòu)、分類、異構(gòu)和命名(structure, classification, isomerism and nomenclature of amines) 326 10.2.2 胺類的物理性質(zhì)和波譜 (physical properties and spectrum of amines) 330 10.2.3 胺類的化學(xué)性質(zhì)(chemical properties of amines) 331 10.2.4 季銨鹽和季銨堿 (quaternary ammonium salt and quaternary ammonium hydroxide) 338 10.2.5 多元胺(polyamines) 340 10.2.6 胺的制備(preparation of amines) 340 10.2.7 重氮和偶氮化合物(diazonium salt and azo compound) 341 10.3 禁用染料(prohibited dyes) 346 習(xí)題(Problems) 347 第11章 雜環(huán)化合物 349 11.1 分類和命名(classification and nomenclature) 349 11.2 呋喃、噻吩、吡咯 (furan, thiophene and pyrrole) 351 11.2.1 呋喃、噻吩、吡咯的結(jié)構(gòu) (structure of furan, thiophene and pyrrole) 351 11.2.2 呋喃、噻吩、吡咯的物理性質(zhì)(physical properties of furan, thiophene and pyrrole) 352 11.2.3 呋喃、噻吩、吡咯的化學(xué)性質(zhì)(chemical properties of furan, thiophene and pyrrole) 353 11.2.4 呋喃、噻吩、吡咯的制備(preparation of furan, thiophene and pyrrole) 354 11.3 吡啶(pyridine) 355 11.3.1 吡啶的結(jié)構(gòu)(structure of pyridine) 355 11.3.2 吡啶的物理性質(zhì) (physical properties of pyridine) 355 11.3.3 吡啶的化學(xué)性質(zhì)(chemical properties of pyridine) 355 11.3.4 吡啶的制備(preparation of pyridine) 357 11.4 其他雜環(huán)化合物 (other heterocyclic compound) 357 習(xí)題(Problems) 360 第12章 天然有機(jī)化合物 362 12.1 糖類(carbohydrates) 362 12.1.1 糖類的分類(classification of carbohydrates) 362 12.1.2 單糖(monosaccharides) 363 12.1.3 二糖(disaccharides) 371 12.1.4 多糖(polysaccharides) 373 12.1.5 異頭效應(yīng)與糖類的構(gòu)象(anomeric effect and conformation of carbohydrates) 375 習(xí)題(Problems) 376 12.2 氨基酸(amino acid) 377 12.2.1 氨基酸的分類和命名(classification and nomenclature of amino acid) 377 12.2.2 氨基酸的結(jié)構(gòu)(stucture of amino acid) 379 12.2.3 氨基酸的化學(xué)性質(zhì)(chemical properties of amino acid) 380 12.2.4 氨基酸的制備(preparation of amino acid) 382 12.3 蛋白質(zhì)(protein) 383 12.3.1 蛋白質(zhì)的分類和結(jié)構(gòu)(classification and structure of protein) 383 12.3.2 蛋白質(zhì)的理化性質(zhì)(physical and chemical properties of protein) 386 12.4 類脂和生物堿(lipids and alkaloids) 388 12.4.1 油脂(natural oils) 388 12.4.2 蠟(waxes) 390 12.4.3 萜類(terpenes) 390 12.4.4 甾族化合物(steroids) 392 12.4.5 生物堿(alkaloids) 393 參考文獻(xiàn) 396
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